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991.
992.
A First‐Cycle Coulombic Efficiency Higher than 100 % Observed for a Li2MO3 (M=Mo or Ru) Electrode 下载免费PDF全文
Jihyun Jang Youngjin Kim Oh B. Chae Taeho Yoon Sang‐Mo Kim Hyun‐seung Kim Hosang Park Prof. Ji Heon Ryu Prof. Seung M. Oh 《Angewandte Chemie (International ed. in English)》2014,53(40):10654-10657
The lithiation/de‐lithiation behavior of a ternary oxide (Li2MO3, where M=Mo or Ru) is examined. In the first lithiation, the metal oxide (MO2) component in Li2MO3 is lithiated by a conversion reaction to generate nano‐sized metal (M) particles and two equivalents of Li2O. As a result, one idling Li2O equivalent is generated from Li2MO3. In the de‐lithiation period, three equivalents of Li2O react with M to generate MO3. The first‐cycle Coulombic efficiency is theoretically 150 % since the initial Li2MO3 takes four Li+ ions and four electrons per formula unit, whereas the M component is oxidized to MO3 by releasing six Li+ ions and six electrons. In practice, the first‐cycle Coulombic efficiency is less than 150 % owing to an irreversible charge consumption for electrolyte decomposition. The as‐generated MO3 is lithiated/de‐lithiated from the second cycle with excellent cycle performance and rate capability. 相似文献
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Seung Hee Yoon Jicheol Shin Hyun Ah Um Tae Wan Lee Min Ju Cho Yong Jae Kim Young Hoon Son Joong Hwan Yang Geesung Chae Jang Hyuk Kwon Dong Hoon Choi 《Journal of polymer science. Part A, Polymer chemistry》2014,52(5):707-718
Novel photo‐crosslinkable hole‐transport and host materials incorporated into multilayer blue phosphorescent polymer light‐emitting diodes (Ph‐PLEDs) were demonstrated in this study. The oxetane‐containing copolymers, which function as hole‐transport layers (HTL), could be cured by UV irradiation in the presence of a cationic photoinitiator. The composition of the two monomers was varied to yield three different hole‐transporting copolymers, [Poly(9,9′‐(5‐(((4‐(7‐(4‐(((3‐methyloxetan‐3‐yl)methoxy)methyl)phenyl)octan‐3‐yl)benzyl)oxy)methyl)?1,3‐phenylene)bis(9H‐carbazole)) ( P(mCP‐Ox)‐I , ‐II , and ‐III )]. In addition, monomer 1 was copolymerized with styrene to produce copolymer P(mCP‐Ph) as a host material for bis[2‐(4,6‐difluorophenyl)pyridinato‐C2,N](picolinato)iridium(III) (FIrpic), a blue‐emitting dopant. All mCP‐based copolymers displayed high glass transition temperatures (Tg) of up to 130–140 °C and triplet energies of up to 3.00 eV. The blue Ph‐PLEDs exhibited a maximum external quantum efficiency of 2.55%, in addition to a luminous efficiency of 8.75 cd A?1 when using the device configuration of indium tin oxide/poly(3,4‐ethylenedioxythiophene):poly(styrene sulfonate)/ P(mCP‐OX)‐III / P(mCP‐Ph) :FIrpic(15 wt %)/3,3′‐[5′‐[3‐(3‐pyridinyl)phenyl][1,1′:3′,1′′‐terphenyl]‐3,3′′‐diyl]bispyridine/LiF/Al. The device bearing P(mCP‐Ox)‐III HTL, containing the highest composition of mCP unit, exhibited better performance than the other devices, which is attributed to induction of more balanced charge carriers and carrier recombination in the emissive layer. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 707–718 相似文献
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In‐Yup Jeon Hyun‐Jung Choi Loon‐Seng Tan Jong‐Beom Baek 《Journal of polymer science. Part A, Polymer chemistry》2011,49(12):2529-2537
We reported the functionalization of multiwalled carbon nanotube (MWCNT) with 4‐aminobenzoic acid by a “direct” Friedel–Crafts acylation reaction in a mild polyphosphoric acid (PPA)/phosphorous pentoxide (P2O5) medium. The resulting 4‐aminobenzoyl‐functionalized MWCNT (AF‐MWCNT) was used as a platform for the grafting of polypyrrole (PPy) in ammonium persulfate (APS)/aqueous hydrochloric acid solution to produce PPy‐grafted MWCNT (PPy‐g‐MWCNT) composite. After dedoping with alkaline treatment, PPy‐g‐MWCNT displayed 20 times higher electrical conductivity than that of PPy. The current density and cycle stability of PPy‐g‐MWCNT composite were also remarkably improved compared with those of PPy homopolymer, suggesting that an efficient electron transfer between PPy and MWCNT was possible through covalent links. In addition, PPy‐g‐MWCNT displayed high electrocatalytic activity for oxygen reduction reaction (ORR). © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
995.
Hye Sun Shin Ik Jun Jang Na Ra Shin Su Hyun Kim Sung June Cho 《Research on Chemical Intermediates》2011,37(9):1239-1246
Dealumination of the small-pore zeolite chabazite (CHA) was performed with ammonium hexafluorosilicate under solid and liquid-state conditions to increase the Si-to-Al ratio from 2.0 to 6.0. In the solid state, the mesopore fraction increased with repeating hydrothermal synthesis at 423 K, which was confirmed by nitrogen adsorption?Cdesorption. In the liquid state, the formation of mesopores decreased substantially and the resulting CHA had an Si-to-Al ratio of ca. 5. The result of desorption of NO?CNO2 from the Cu ion-exchanged dealuminated CHA in the solid state indicated that the presence of mesopores reduced NO?CNO2 adsorption and desorption of NO2 occurred at 383 and 683 K whereas for the high-silica analog SSZ-13 desorption of NO2 occurred mostly at 473 and at 673 K. 相似文献
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Arul N. Sabari Cavalcante L. S. In Han Jeong 《Journal of Solid State Electrochemistry》2018,22(1):303-313
Journal of Solid State Electrochemistry - In this study, we have reported a facile fabrication of pristine zinc sulfide (ZnS), manganese sulfide (MnS), and ZnS/MnS nanocomposites (NCs) via... 相似文献
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This article has been retracted: please see Elsevier Policy on Article Withdrawal (http://www.elsevier.com/locate/withdrawalpolicy).This article has been retracted at the request of the corresponding author. The corresponding author prepared a series of cinchonine derivatives and found that the structure of PCA, which was a major compound, was mistakenly assigned. The synthetic routes, physical and spectroscopic data for the products are valid. As a result the corresponding author withdraws this publication. 相似文献